A2-Level Transition Elements
The d-orbitals in a transition metal atom can be split into high energy and low energy orbitals. This creates an energy gaps between the two sets of orbitals.
Electrons from lower energy d-orbitals can be excited to higher energy d-orbitals by absorbing energy.
White light contains waves of electromagnetic radiation that have different energies and colour.
If the energy required to excite an electron can be found in white light, specific wavelengths of light are absorbed by the transition metal and are removed from the white light.
The complimentary colour of the wavelengths absorbed is now observed and the transition metal has a ‘colour’.
Transition Elements Colour
All five d-orbitals have complicated shapes that occupy different areas around a nucleus. When ligands move towards a metal ion, some orbitals are closer to the ligand than others and so experience more repulsion – this makes them higher in energy compared to the other d-orbitals.
The d-orbitals energies are split – some orbitals are high energy, some are low energy.
Transition elements form ions that have partially filled d-subshells, this means there will always be a d-orbital that has a space for an electron.
Lower energy orbitals are always filled first, and then the higher energy levels are filled once the lower orbitals are full. So, it’s the higher energy orbitals that have a space for an electron.
If just the right amount of energy is given to an electron in a lower energy orbital, it can become excited and go into a partially filled high energy orbital. The amount of energy required for this to occur is very specific and it’s different for every metal ion.
Excited electrons can also lose energy and go back to a lower energy orbital. The energy lost by the electron is ‘emitted’ as light of a particular wavelength. This is how organic molecules can produce light (fireflies, for example). A chemical reaction excites the electrons to a higher energy d-orbital; then as the electrons fall to a lower energy orbital, energy is released as light.
Light is part of the electromagnetic spectrum – a large range of waves that transmit energy from one place to another. The sun emits electromagnetic radiation, some of which is visible to us as light. It is very important to recognise that visible light is just particular wavelengths of electromagnetic radiation. The range of wavelengths that humans can see is called the visible region of the electromagnetic spectrum.
White light contains all wavelengths in the visible region and has no observable colour. If any colour is removed then it’s no longer white light, and a colour is observed. Different colours of light have different wavelengths and are different energies. Violet light is the highest energy; red light is the lowest energy.
With most transition metal ions, the energy gaps between high and low energy orbitals fall within the visible region of the electromagnetic spectrum. This allows ‘light waves’ to excite electrons from low energy d-orbitals to high energy d-orbitals. When this happens, the transition metal ion absorbs the wavelength of light that matches the energy gap between its d-orbitals, and this colour of light is removed from the white light.
Removing a colour from white light means the light now has an overall colour and can be observed.
The colour observed when a particular colour is removed from white light is called its complimentary colour. For example, if orange light is absorbed by a transition metal ion then all the other colours in white light are reflected (or transmitted), and the colour observed is a combination of them all. In this case, blue would be the colour seen.