Isotopes
Specification Reference Physical Chemistry, Atomic Structure 1.2
Quick Notes
- Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons.
- Notation: Isotopes are shown as nZX or X-A, where:
- Z = atomic (proton) number
- A = mass (nucleon) number
- Chemical properties are the same for all isotopes of an element (same electron configuration).
- Physical properties (e.g. mass, density) differ between isotopes due to different numbers of neutrons.
Full Notes
What Is an Isotope?
Isotopes are atoms of the same element that have the same number of protons but different numbers of neutrons. This means they have the same atomic number but different mass numbers.
For Example:Carbon has naturally occurring isotopes:

- Carbon-12 (6 protons, 6 neutrons)
- Carbon-13 (6 protons, 7 neutrons)
All are carbon because they have 6 protons.
Isotope Notation
Isotopes are represented using nuclear notation: nZX or X-A
- Where X = chemical symbol, Z = atomic number (number of protons), and n = mass number (protons + neutrons).
Examples:
- C-12 = carbon-12
- O-16 = oxygen-16
- Cl-35 = chlorine-35
Chemical Properties of Isotopes
All isotopes of the same element have the same chemical properties. This is because chemical reactions involve electrons, and isotopes have the same number of electrons and the same electron configuration.
Physical Properties of Isotopes
Isotopes have different physical properties, such as mass and density. This is due to the different number of neutrons, which affects the atom’s total mass.
Summary
- Isotopes: same number of protons, different numbers of neutrons.
- Nuclear notation: nZX or X-A (A = protons + neutrons, Z = protons).
- Chemical properties are identical across an element’s isotopes (same electron configuration).
- Physical properties differ because isotopes have different masses.