Electroplating and Electrode Reactions HL Only
Specification Reference R3.2.16
Quick Notes
- Electroplating uses an electrolytic cell to deposit a thin metal layer onto an object.
- The object to be plated is the cathode (negative electrode).
- The anode is usually made of the metal being plated.
- The electrolyte is a solution containing ions of the plating metal.
- Reduction occurs at the cathode where metal ions gain electrons and are deposited.
- Oxidation occurs at the anode where metal atoms lose electrons to replenish ions in solution.
Full Notes
Electroplating is a process that uses electrolysis to coat the surface of a metal object with a thin layer of another metal.
It’s widely used for a variety of reasons - such as to improve the appearance or prevent corrosion.
Basic Setup of an Electrolytic Cell for Electroplating

Components:
- Cathode: object to be plated (e.g. a spoon)
- Anode: metal to be deposited (e.g. silver or copper)
- Electrolyte: aqueous solution containing metal cations (e.g. Ag+ or Cu2+)
- Power supply: provides direct current (DC)
Current flow: Electrons flow from the anode to the cathode via external circuit.
Example: Silver Electroplating
Example Silver Electroplating
Cathode (reduction): Ag+(aq) + e⁻ → Ag(s)
(Silver ions from solution are deposited on the object)
Anode (oxidation): Ag(s) → Ag+(aq) + e⁻
(Silver anode gets smaller and Ag+ replenished in solution)
Net result: A thin layer of silver builds up on the cathode.
Other Common Electroplating Reactions
- Copper electroplating:
- Cathode: Cu2+(aq) + 2e⁻ → Cu(s)
- Anode: Cu(s) → Cu2+(aq) + 2e⁻
- Nickel electroplating:
- Cathode: Ni2+(aq) + 2e⁻ → Ni(s)
- Anode: Ni(s) → Ni2+(aq) + 2e⁻
Summary
- The cathode gains metal coating by reduction of metal ions.
- The anode loses metal atoms by oxidation, maintaining ion concentration.
- Electroplating is used for protective coating, decorative purposes, and corrosion resistance.